Palladium, [1,3-bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene]chloro[(1,2,3-h)-(2E )-3-fenil-2-propen-1-yl]-,stereoisomer Cas:884879-23-6
Nomer Katalog | XD90699 |
Jeneng produk | Palladium, [1,3-bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene]chloro[(1,2,3-h)-(2E )-3-fenil-2-propen-1-yl]-,stereoisomer |
CAS | 884879-23-6 |
Formula Molekul | NeoalystCX31 |
Bobot Molekul | - |
Rincian panyimpenan | Suhu Kamar |
Spesifikasi Produk
Assay | 99% |
Titik lebur | 205-208°C |
Panggunaan komplek [(NHC)Pd(R-allyl)Cl] generasi kapindho kanggo reaksi kopling silang Suzuki-Miyaura lan Buchwald-Hartwig sing nglibatake halida heteroaromatik ing suhu kamar dilaporake.Conto pisanan saka suhu kamar Suzuki-Miyaura cross-coupling saka aril klorida sing dipateni karo asam alkenyl boronic uga dibeberke.Substitusi terminal ing gugus alil kompleks paladium nggampangake aktivasi ing suhu kamar sing ndadékaké spesies katalitik sing aktif banget, saéngga transformasi katalitik saiki bisa ditindakake kanthi cepet nggunakake kondisi reaksi sing entheng.Muatan katalis bisa nganti 10 ppm kanggo aminasi aril Buchwald-Hartwig lan 50 ppm kanggo reaksi Suzuki-Miyaura.
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